压裂施工完成后,传统的工序是将压裂球返排至地面,但有时存在由于地层压力不足或球变形等导致压裂球卡死在通道内而无法返排至地面的情况,此时需要下钻磨铣球和球座,否则将严重影响油井产量。使压裂球具备可分解功能成为解决这个问题的有效办法之一,即压裂作业完成后压裂球可自行分解,从而可以免去返排或磨铣工序,消除了压裂球阻塞通道的可能性。
为适应投球滑套分段压裂需求,可分解压裂球需同时具备两方面特点:一是在地层水等电解质液体中可自行快速分解,二是在地层较高温度下具有较大的强度。
石油圈曾介绍过Phenom Innovations公司的一款Wraith可降解压裂球。该技术可在超过100℉的环境下,在任何一种水溶液中完全降解,降解速率可根据不同条件提前设定,为后续完井作业减少了大量的工序,节约了作业成本。
2014年,Terves公司推出了第二代TervAlloy可分解压裂球。近期该公司宣称,第二代TervAlloy可分解压裂球已经广泛应用,在北美的水平井压裂完井中得以施展拳脚。本文将对该技术的性能进行详细介绍。
与上一代可溶性压裂球金属相较,新一代的压裂球由TervAlloy™镁铝纳米复合材料制成,通过控制流体(例如电解质)、电激励或热激励进行分解。TervAlloy™纳米复合压裂球强度更高,且强度保持时间更长,以保证长时间压裂作业的实施,储存与处理更加方便,不容易发生过早退化,已在超过75000级的压裂作业中得以成功应用。
Terves公司创始人兼首席技术官Andrew Sherman,于2015年4月22日在卡尔加里召开的首届加拿大页岩技术大会上介绍了此次创新成果。该次会议由Gulf Publishing公司下属的世界油气杂志(World Oil magazine)和DMG Events传媒公司承办,是一届页岩气专业人士与专家深入探讨行业发展前景和最新技术进展的高层论坛。
高强度,可溶解
Sherman在演讲中会详细阐述了纳米复合金属材料的诸多技术特性:比铝更轻且更强韧,当暴露在井下高温完井液中时将以高度可控方式完成分解过程,化百炼钢为绕指柔,保证井筒“畅通无阻”。石油圈原创www.oilsns.com
迄今为止,高强度可分解压裂球主要应用于油田的滑动套筒完井作业中。最近,新型压裂球应用触角延伸至桥塞和射孔完井作业中。
依托新一代高强度、低成本的纳米复合金属技术,贯眼可溶解性作业工具研发步伐大幅加快。Terves公司具备专利性的纳米复合金属技术,在可溶解金属压裂球与类似特性的完井工具供应商内扮演着“领头羊”的角色。
与低强度可溶性聚合物或初代可溶性金属压裂球相比,新一代镁铝合金压裂球在投球到位过程中可保持外形稳定且不会发生分解,抗拉强度可达45000psi,当泵送压力超过10000psi后可有效驱动压裂滑套或密封压裂桥塞。
一旦投递到位,TervAlloy™镁铝纳米复合材质压裂金属球在完井液和井底温度(85℉-200℉)作用下可降解为可溶性微米颗粒,利于从井筒循环排出。压裂完井后经过1-5天,新型工具已经完全降解,井筒“畅通无阻”,后期无需连续油管作业。
TervAlloy™镁铝纳米复合压裂金属球由五种配方加工而成,在不同完井液体系和井底温度下的降解速率不同。两种涂层材料使得压裂球在降解阶段可联合开展酸化作业,或在触发媒介进入井筒前防止压裂球的完全降解。石油圈原创www.oilsns.com
“鉴于TervAlloy™镁铝纳米复合压裂金属球在油田中的成功应用,Terves公司乘胜出击,与多家油田服务公司合作,提供专利技术指导,研发出其他类似的可溶性完井工具,比如滑套球座、完全溶解性压裂暂堵剂、可分解桥塞、预射孔衬管以及厚壁短管等。”Sherman说道。
“Terves公司一直致力于研究新型材料及应用,包括防砂筛管、提高压裂导通性技术、遇淡水可分解的用于海上生产井的高比重盐水以及强度更高的小尺寸合金球(减小质量,从而降低成本)。”他又说道。石油圈原创www.oilsns.com
“可分解压裂球的应用降低了后续连续油管作业的必要性,可显著降低运营商的施工成本。”
Tervalloy合金在盐水、酸、淡水以及溴化钙(海上生产井所用媒介)中,可通过可控、可靠的方式完成分解。同时,可形成拱形支架或渗透到工具内部(防砂):
- 可泵送应用;
- 示踪剂/化学药剂释放;
- pH值控制;石油圈原创www.oilsns.com
- 液流转向。
Tervalloy系列工具能够与当前套筒配合使用,可加工成多种形状。金属球和其他完井工具的加工误差均可控制在0.003英寸的精度范围内。新型工具的应用可减少清理井筒及循环成本,显著节约成本并提高生产速度。
作业期间必需更高的压差?TervAlloy高强度压裂球和其他完井工具给出的答案是否定的。
- 活性弹头和导弹应用;
- 高强度压裂球;石油圈原创www.oilsns.com
- 标准化高强度完井工具,比如套筒、筛管和气缸;
- 桥塞、销子、阀门、杆、螺丝和油管;
- 满足任意机械加工、挤压或冲压方式;可溶性增强型完井工具;
- 利用压裂酸触发套管射孔;
- 可溶性药型罩/爆炸成型穿透弹药(EFP,Explosively Formed Penetrator);
- 高密度结构性能量。石油圈原创www.oilsns.com
“可降解压裂球的应用,可避免投球不到位问题并减少清理井筒及循环成本,从而为运营商显著节约成本。”Sherman说。
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来自/Tervalloy 译者/姚园 编辑/Leia
Terves Inc. announced that more than 500 of its second-generation TervAlloy engineered disintegrating frac balls have been successfully deployed in horizontal frac completions in North America since their introduction in late 2014.
These new, lower-cost and higher strength metallic tools are easier to store and handle and less prone to early degradation than prior generation dissolvable metals, which have been used on more than 75,000 frac stages over the last three years.
The announcement coincides with a scheduled presentation by Andrew Sherman, Terves Inc.’s founder and Chief Technology Officer, at the inaugural ShaleTECH Canada conference in Calgary on April 22, 2015. The conference, sponsored by Gulf Publishing’s World Oil magazine and DMG Events, will be a high-level forum for shale gas professionals to hear experts discuss the industry outlook and the latest technology advancements for shale gas development.
Advantages of High Strength Dissolvable Metals
In his presentation, “Emerging High Strength Dissolvable Materials,” Mr. Sherman will review the technical principles of nanocomposite metals, which are lighter and stronger than aluminum, and which are engineered to disintegrate in a highly controllable manner when exposed to completion fluids at downhole temperatures.
To date, the main oilfield application for high strength dissolvable materials has been for dissolvable frac balls used with sliding sleeve completions. More recently, dissolving balls have been deployed with bridge plugs for plug and perf completions.
Full bore dissolvable tools are just emerging, enabled by the higher strength and lower cost of the next-generation materials. Terves has proprietary and patented nanocomposite technology and is a leading supplier of disintegrating magnesium frac balls and completiontool components.
Unlike balls made of less rigid dissolvable polymers and prior generation dissolvable metals, these engineered magnesium alloy frac balls maintain their shape and do not start degrading in the ball drop system, while effectively actuating sleeves or sealing frac pugs at pumping pressures that can exceed 10,000 psi.
Once deployed, the engineered alloy tools respond to a combination of completion fluids and bottomhole temperatures of 85℉ to 200℉ to degrade into soluble micron-sized particles that easily circulate out of the well. Within 1-5 days after the frac completion, tools are completely disintegrated, leaving an unobstructed wellbore, without requiring coiled tubing drill out operations.
“Disintegrating frac balls create significant savings for operators by preventing ball hang-up problems and reducing drill out and circulating costs,” Mr. Sherman said.
Five formulations of TervAlloy “Engineered Response” Magnesium Alloys are available with useable tensile strengths up to 45,000 psi and with a range of dissolution rates engineered for different completion fluids and well temperatures. Two coating materials also are available to enable acid treatments with the disintegrating balls/stages in place, or to delay disintegration completely until a triggering solution is introduced into the well.
“With TervAlloy’s advantages field-proven in frac ball applications, Terves continues to work with oilfield service companies and tooling OEM’s to deploy dissolvable metals for construction of other completions components, including sliding sleeve ball seats, fully dissolvable frac plugs, disintegrating bridge plugs, slips and grips, pre-perforated liners, and short tubular sections,” Mr. Sherman added.
“The company’s research and development efforts also include work on new materials and applications, including sand screens and fracture conductivity enhancement, freshwater dissolvables, dissolvables designed specifically for use with heavy brines in offshore wells, and even higher strength alloys to enable smaller seats and reduced component mass to further reduce costs,” he said.
“Dissolvable frac balls save operators time and money by reducing the need for coiled tubing drill out operations.”
Tervalloy alloys dissolve in a controlled, reliable manner
- Brine;
- Acid;
- Freshwater;
- CaBr/offshore.
Can be overcast or infiltrated into tools (sand control)
- Pumpable versions in development;
- Tracer/chemical release;
- pH control;
- Flow diversion.
The TervAlloy system is compatible with existing sleeves and can be machined into a variety of shapes. Balls and other components can be machined and kept to tolerances of 0.003”. Eliminate drillouts and flowback. Harness the cost savings and increased production speed that dissolvable tools offer.
Need higher pressure differentials? TervAlloy High Strength frac balls, tools & tubulars available.
- Reactive Warheads and Missile Cases;
- High strength Frac Balls;
- Standard and high-strength completion tools like sleeves, screens and cylinders;
- Plugs, pins, gates/valves, rods, screws and tubing;
- Any machinable, extrudable, or stampable form;
- Dissolvable enhanced completion tools;
- Triggered perforated sleeve with integral fracture aids;
- Dissolving/disintegrating shaped charge liners/EFP’s;
- High density Structural energetics (consumable cases, reactive fragments/EFP’s).
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