水是万物之源,更是页岩油气持久发展的关键。
来自 | E&P
编译 | 张德凯
Mark Wolf 是NOV公司Process and Flow Technologies部门陆地设施的负责人,在水处理技术方面经验非常丰富。他表示:“Permian Basin的页岩开发商正在带领油气行业走出低潮,但是目前该地区没有充足的水源以供钻井、压裂等作业使用,所以水处理、储存、运输、回收利用等问题将会非常关键,决定着该地区油气开发是否能够成功。”
水处理公司CH2M 副总裁Michael Dunkel表示:“我相信,油气开发过程涉及的水处理技术将会迅速发展,成本更低、可持续性更强的方案在今后几年将会逐渐问世。”
专业建议,识别废水处理危险系数
美国一家咨询顾问公司近日发布了一本300页的分析报告,主要包括两方面内容:
1)水利用/处理过程危险系数识别与量化;
2)为了更加安全有效的处理采出水、压裂用水、其它油田废水及保护饮用水源,油气行业对于二类盐水注入井的使用/依赖趋势。
目前,关于废水回注地下的应用与环保法规要求互相矛盾,这些主要由于政治因素引起。该公司从公正及事实的角度出发,根据详细的地区划分,从局部、区域及地方角度对废水回注地下(UIC)法规进行了分析,以相对风险系数对不同操作和设备进行了标识,根据书中所含图表、目录,操作人员即可识别危险系数更高、有待进一步详细调查/消除危险的设备和UIC区域。
这份调查报告中详细报道了美国主要陆地油田的废水回注状况,还进行了代表地区的区域性分析,包括特殊回注状况、地区地震属性、油藏危险系数、 技术基础、法规与诉讼情况、操作连续性、最佳执行方式、地域性降低危险方式以及最新的投资趋势等。
新型处理工具,降低水处理成本
Veolia公司的ShaleFlow系统是一个经济、可移动的采出水/回流水处理系统,结构紧凑,便于运输,采用三拖车配置,随着作业现场的不断变化,其位置也可随之改变,应用灵活性高。ShaleFlow的处理能力达到10000bbl/d,且可处理废水种类多,可溶性固体废物含量上限达300000mg/L。该系统将固体颗粒和易结垢的物质水平降低,废水处理后完全满足压裂和完井作业要求。
水处理和重复利用能够降低新鲜水源的需求量,同时还能达到回收原油、降低采出水处理成本的目的。今年Veolia还推出了另一款产品CoStrip,主要用于去除废水中的溶解气体,包括BTEX(苯、甲苯、乙苯和二甲苯)、挥发性有机化合物、CO2和H2S,且该过程完全不需要废水预处理流程。CoStrip通常作为满足地表排放标准废水处理线的一部分使用,对于降低成本具有明显的作用。若与化学软化剂配合使用,CoStrip还能有效降低化学药剂和泥浆成本,并延长反向渗透膜的使用寿命。
加速废水处理设施建设,降低成本
Victaulic HDPE系统安装简便、迅速,Atlas Resources公司的Hamman盐水处理设置在10天内就完成了安装,而传统技术则需要六周
Victaulic联接系统不含熔融工艺,专用于高密度聚乙烯(HDPE)管件的连接,主要包括小/大直径联轴器、适配器、过度转换器及相关附件。将Victaulic HDPE用于SDR7与21HDPE的管件联接速率更高,是采用熔融方案连接水/泥浆管线的10倍。Victaulic消除了连接作业中的熔融操作,管件对接更加快速、简单,且其应用范围也非常广,在液体流动管线、输水、压裂液储池、水处理、废弃盐水处理以及相关设施建设方面都能发挥巨大作用。
当前,页岩开发采出水运输和处理成本已经到达整体开发成本的一半左右,是开发商面临的最主要降本挑战。为了控制成本,开发商开始选择建立独立的油气开采和废水处理设施,取代了第三方水废水处理公司的加入。Victaulic的HDPE系统能够帮助开发商更加快速地完成废水处理设施的建设,同时降低整体安装成本。Victaulic的联轴器无论是在垂直方向还是空间受限的区域都能快速链接。此外,联轴器还可以回收重复利用,进一步降低了成本。Victaulic的无熔融工艺管件联接系统在多处页岩油藏得到了成功应用,其中包括Permian和Eagle Ford。
页岩开发回流水处理技术消除钝化现象
页岩开发回流水电凝处理(EC)的应用要追溯到2000年左右,EC技术是众多回流废水处理工艺的核心。EC具有破乳作用,可溶/不可溶的碳氢化合物、重金属、悬浮固体颗粒、有机物、细菌的移除率可达98%以上。然而传统的EC方式都存在着一个明显的问题—钝化。钝化会导致氧化结垢,系统的电极表面也会生成一层钝化膜,造成显著的人工成本、能耗增加,降低处理效率和处理量。一旦发生钝化现象,废水处理效率会成指数下降,开发商就不得不停机进行清洗或电极更换,成本极高。为了解决该问题,Water Vision推出了专利型ThinCell EC技术,能够完全避免了钝化问题的发生。
ThinCell EC采用消耗电极,分解后只会生成常规废物,电极完全消耗后,只需更换一个新的电极,不会发生设备长时间停机的问题,且电极成本可控。ThinCell EC的清洁和电极更换过程不涉及钢板等部件的去除操作。钝化现象的消除稳定了操作所需电流,降低了动力需求和应用标准。ThinCell技术增加了EC废水处理设备的连续运行时间,降低了设备维修频率及相关成本、风险。得益于该技术的问世,ThinCell的设备规模得到控制,且具有多种配置,处理流量范围覆盖5~500gal/min,灵活性极高。
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REPORT IDENTIFIES AND QUALIFIES SALTWATER RISK FACTORS, TRENDS
The EnergyMakers Advisory Group is publishing a comprehensive 300-page metastudy that identifies and qualifies the complex risk factors and recent trends associated with the oil and gas industry’s operational reliance on Class II saltwater disposal wells for the safe and effective disposal of produced water, fracturing water and approved oilfield liquid wastes as well as protection of U.S. drinking water sources. There is a complex array of conflicting information surrounding use and regulation of underground disposal wells, often with politically driven undertones. In an even-handed, fact-based manner, The EnergyMakers Advisory Group explores these underground injection control (UIC) issues at a macro, regional and local level supported by detailed maps, relative risk weighting factors, and charts and indices allowing operators to identify those assets and UIC formations with higher relative risk that may bear more detailed exploration or risk mitigation. The coverage universe includes a deep dive into each of the leading onshore U.S. basins covering basin and region-specific injection, seismicity, formation health risk indicators, scientific underpinnings, regulatory and litigation landscapes, operations continuity and best practice considerations, region-specific opportunities for risk reduction, and new investment frontiers.
TOOLS REDUCE WATER MANAGEMENT COSTS
Veolia has developed ShaleFlow, a cost-effective mobile system for treatment and reuse of flowback and produced water from hydraulic fracturing operations. This compact, transportable system incorporates proven technologies in a three-trailer configuration with the flexibility to be moved as the field is developed. ShaleFlow can treat up to 10,000 bbl/d and accept a wide range of influent water quality containing up to 300,000 total dissolved solids. The system removes particulates and scale-formers to low levels, generating water quality suitable for reuse in fracturing and completion operations. Water treatment and reuse reduces freshwater demand, recovers oil from produced water and minimizes produced water disposal costs. Another Veolia product released this year is the CoStrip degasifier. CoStrip effectively removes dissolved gases such as BTEX (benzene, toluene, ethylbenzene and xylene), volatile organic compounds, CO2 and H2S without the need for pretreatment. Typically installed as part of a treatment train that enables surface water discharge, CoStrip minimizes the capex and opex costs of the overall system. Its effective operation reduces chemical and sludge costs when paired with chemical softening and extends the life of reverse osmosis membranes.
BUILD SALTWATER DISPOSAL FACILITIES FASTER WITH LOWER OVERALL COSTS
The Victaulic Refuse-to-Fuse joining system for high-density polyethylene (HDPE) pipe is a line of small and large-diameter couplings, fittings, transitions and accessories that can join SDR 7 to 21 HDPE pipe up to 10 times faster than fusion—the common method used in connecting water and slurry HDPE lines. The Victaulic system eliminates the need for fusion, providing a faster, simpler joining method that can be used in a variety of applications including flowlines, water transportation, fracturing ponds, water treatment, saltwater disposal and facility construction. Produced water transportation and disposal costs can represent half of a shale well’s operating expenses and is one of the biggest challenges facing an operator’s bottom line. To put a lid on these costs, operators are building their own production and water disposal facilities instead of relying on third-party waste management companies. Victaulic’s HDPE system is helping shale operators build saltwater disposal facilities faster with lower overall installed costs. The couplings can be easily installed in vertical orientations as well as in tight spaces using simple hand tools and can be reused from site to site. Victaulic’s Refuse-to-Fuse system has been successfully deployed by major operators in several shale plays, including the Permian and Eagle Ford.
SHALE FLOWBACK FLUIDS TREATMENT ELIMINATES PASSIVATION
Electrocoagulation (EC) treatment for shale play well flowback fluids dates back to the early 2000s. Its role is the heartbeat in many flowback fluid treatment processes. It breaks emulsions and reduces insoluble and soluble hydrocarbons, heavy metals, suspended solids, organics and bacteria concentrations at efficiencies exceeding 98%. Traditional EC methods, however, have a problem— passivation. This detrimental challenge causes oxide scale or coating buildup on the system’s electrodes, adding significant costs in manpower, power consumption, efficiency and disposal. Passivation can quickly cause treatment efficiency degradation and shutdown for costly electrode (plate) cleaning or replacement. Water Vision Inc. has developed a proprietary ThinCell EC technology that completely eliminates passivation. The technology uses sacrificial electrodes consisting of a common waste product that are completely consumed and efficiently replenished without costly unit downtime. There is no need for electron/ plate removal for cleaning (acid wash or grinding) or replacement. Passivation elimination preserves the necessary electrical amperage for the cell operation, lowering power requirements and usage. ThinCell technology increases uptime, reduces maintenance and lowers both costs and safety risks. Because of its technology, the ThinCell has a small footprint and is available in a variety of mobile configurations and flow rates from five to greater than 500 gal/ min.
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