世界虽然掀起了页岩气热潮,但是欧洲各国却对待页岩气的态度迥异。与常规天然气开采相比,页岩气开采增加了水力压裂过程,在水力压裂过程中,主要涉及水资源的利用、压裂液对地下水和地质的影响以及返排压裂液排放对地表水的影响。
水力压裂用水量巨大,通常单级压裂需要使用约3,769桶水,一口井如果压裂30级,总共将耗费约113,100桶清水。压裂后返出地面的废水,必须经过处理并注入到地下的存储井中。
每口需要压裂的井都需要重复上述过程,但威德福认为压裂措施可以采用更高效的作业方式:全新设计的WaterSure流体系统,可以使用地层产出水或返排水进行压裂,且不影响压裂效果。
事实证明,重复利用废水作为增产流体用于多种井况是可行的,该技术不仅节约了当地的淡水资源,而且降低了成本。
压裂液中的悬浮物和细菌可以抑制压裂效果并伤害地层,将这些不利物质清除后,再向压裂液中添加环保胶凝剂和交联剂,便可以得到干净、低残留、不受返排液中添加剂影响的压裂液。这种压裂液可以使用盐、溶解总固体、二价离子以及硼含量均较高的水直接配置。WaterSure流体具有与淡水相当的导流能力和渗透率特性,有利于保护地层免受伤害。石油圈原创www.oilsns.com
在不影响压裂增产效果的前提下,WaterSure流体系统可以100%使用地层产出水或返排水(过不过滤均可)。在淡水供应紧张或水质较差的作业区域,使用WaterSure系统可以节约淡水资源,降低用水成本。石油圈原创www.oilsns.com
WaterSure流体可以在高温环境下,维持要求苛刻的粘度值,足以保证长时间携带支撑剂。
应用范围石油圈原创www.oilsns.com
- 淡水资源受限、水质较差或处理水成本较高的作业区域;
- 井底温度范围43℃-148℃的作业环境;石油圈原创www.oilsns.com
- 硼含量400ppm、总溶解固体含量307,000ppm、二价离子含量30,000ppm的水;
- 氯和盐含量较高的水。石油圈原创www.oilsns.com
技术特点石油圈原创www.oilsns.com
WaterSure流体可以使用各种类型的水:淡水、过滤或未过滤的地层产出水或返排水。操作人员可以100%使用地层产出水或返排水,可以自由选择是否过滤悬浮固体。
WaterSure使用三种添加剂优化压裂效果:交联剂、pH值调整剂和胶凝剂,不受温度波动、返排液中的添加剂及水质变化的影响,可以在淡水和产出水或返排水之间进行切换。
将二氧化氯(ClO2)添加到WaterSure流体中,有效避免了细菌使井下变成酸性环境,从而提高地层的渗透率、湿度和孔隙度。
同时,WaterSure流体中的胶凝剂采用低分子量聚合物配制而成,可获得更高的粘度值。
其他特点:石油圈原创www.oilsns.com
- WaterSure流体不受抑制凝胶水化离子的影响,缩短了水化时间;
- WaterSure流体与大多数化学品兼容;石油圈原创www.oilsns.com
- 对剪切的不敏感性可以防止WaterSure液体在流动初期提前遭到破坏;
- 过硫酸铵分解剂可使WaterSure流体根据温度和用量以可控的间隔进行分解;
- 测试表明,使用WaterSure系统后,地层渗透率得到极大的恢复(超过84%),从而将地层受到伤害的风险降至最低。
技术优势石油圈原创www.oilsns.com
- 节约淡水资源,压裂作业更环保;石油圈原创www.oilsns.com
- 避免运输淡水相关的诸多问题,如等停、物流、成本和油耗;
- 减少废水处理作业量,无需再钻探和维护存储废水的井;
- 仅通过使用一种交联剂和一种低成本的常规凝胶剂,就可以重复利用地层产出水或返排水,降低了完井成本;
- 降低了对过滤的要求;石油圈原创www.oilsns.com
- 可以可靠地运用于不同的井况;石油圈原创www.oilsns.com
- WaterSure流体具有接近淡水的导流能力和渗透率特性,因此压裂效果与100%使用淡水压裂一样。
WaterSure流体处理工艺
1.过滤悬浮固体石油圈原创www.oilsns.com
在作业者的作业现场可能没有过滤产出水所需的设备,威德福与Omni水处理公司(Omni Water Solutions)合作提供这些设备。现场只需进行简单的化学处理甚至无需化学处理,Omni系统便可以将产出水中影响压裂效果的的全部悬浮固体过滤掉,将水净化至15微米到亚微米级别。
由于干扰离子、盐度、硼、钙和氯化物对WaterSure流体性能没有影响,因此无需去除这些成分,从而降低了处理费用。过滤后的废弃物可以采用环保的方式进行处理。
2.氧化石油圈原创www.oilsns.com
过滤掉悬浮固体后,需要向过滤水中添加对环境无任何危害的二氧化氯(ClO2),杀死将井下环境变成酸性的细菌,同时有利于降低油藏压力、提高地层渗透率、湿度和孔隙度,提高产能的同时,不影响井下pH值的平衡,不与大多数有机物和氨反应。
3.准备压裂石油圈原创www.oilsns.com
最后,向过滤后的水中添加环保胶凝剂和交联剂,形成具有良好支撑剂运输能力和导流能力的流体。WaterSure流体可以使用含盐量高于300,000 ppm、二价离子浓度为5000-30000 ppm、以及硼含量大于400ppm和氯含量185,000 ppm的水。
此外,该流体在38℃-149℃的温度范围内性能表现良好。通过加入专用的交联剂,WaterSure流体可以维持良好的粘度值,足以在高温高压的井底环境下,长时间有效携带支撑剂。
来自/Weatherford 译者/白小明 编辑/Leia
With the average fracturing stage using about 158,300 gallons (3,769 barrels) of water and an average of 30 stages in a well, you likely use about 4.75 million gallons (113,100 barrels) of fresh water per well. Once used downhole and returned to the surface, it is wastewater that requires treatment and injection in an underground storage well. You repeat this process for
every well.
At Weatherford, we think there’s a more efficient way to operate. That’s why we designed the WaterSure™ fluid system. It enables you to fracture using produced or flowback water—without sacrificing performance.
Reuse your wastewater as a key ingredient in stimulation fluids that perform reliably in a variety of downhole conditions, while conserving the local fresh water supply and reducing your costs. Once all suspended solids and bacteria—which could inhibit fracturing performance and damage your well— have been filtered from your produced water, we add an environmentally friendly gelling agent and crosslinker. The result is a clean, low-residue stimulation fluid that is unaffected by flowback additives and can handle waters high in salinity, total dissolved solids (TDS), divalent ions, and boron. WaterSure fluids imitate the conductivity and permeability of fresh water, which protects formations from damage.
Tool Description
The WaterSure® fluid system enables fracturing with 100% produced or flowback water—either filtered or unfiltered—without sacrificing stimulation performance. When freshwater supplies are limited or water quality is inconsistent, use of the WaterSure system conserves freshwater supplies and reduces water costs.
The system adds an environmentally friendly gelling agent and crosslinker to any available water at your wellsite. The result is a low-residue stimulation fluid that is unaffected by flowback additives and can handle waters high in salinity, total dissolved solids (TDS), divalent ions, and boron. WaterSure fluids imitate the conductivity and permeability of fresh water, which protects formations from damage.
This graph shows WaterSure fluids operating in 100% unfiltered produced water. WaterSure fluids maintain high, closely controlled viscosity levels that are sufficient to carry proppant over long periods of exposure to high temperatures.
Applications
- Locations where freshwater sources are limited, where obtaining • consistent;
- water quality can be problematic, or where water conditioning is not an available or cost-efficient option;
- Bottomhole temperatures ranging from 110°F to 300°F (43°C to 148°C);
- Water with up to 400 parts per million (ppm) of boron, 307,000 ppm of total dissolved solids (TDS), and 30,000 ppm of divalent ions;
Water with unlimited levels of chloride and salt.
Features
- WaterSure fluids can incorporate all types of water: fresh water and unfiltered or filtered produced or flowback water. Operators can use up to 100% produced or flowback water, and filtering suspended solids from the water is optional;
- Three additives enable optimal fracturing performance: crosslinker, pH leveladjuster, and gelling agent. As a result, WaterSure fluids are unaffected by temperature fluctuations, flowback additives, and changes in water quality, such as switching between fresh water and produced or flowback water;
- Chlorine dioxide (ClO2) can be added to WaterSure fluids to eliminate bacteria that can sour wells and to improve the permeability, wetness, and porosity of formations.
- WaterSure fluids are unaffected by ions that suppress gel hydration, which reduces hydration time;
- The gelling agent is formulated to yield higher viscosity levels using a lowerweight polymer compared to standard crosslinked fluid systems;
- WaterSure fluids are compatible with a wide range of chemicals;
- Non-sensitivity to shearing prevents WaterSure fluids from breaking down prematurely when motion is applied;
- An ammonium persulfate breaker enables WaterSure fluids to break down in controlled intervals based on well temperature and the pounds of breaker used;
- Tests indicate a high level of regain permeability (more than 84%)—a low risk for formation damage— after using the WaterSure system.
Benefits
- Conserves the freshwater supply for more environmentally – friendly fracturing;
- Eliminates the downtime, logistics, costs, and fuel consumption associated with transporting fresh water;
- Reduces wastewater disposal and the need to drill and maintain storage wells;
- Decreases completion costs by recycling produced or flowback water and by using only one crosslinker and a low-cost, conventional gelling agent;
- Reduces filtration requirements;
- Performs reliably in diverse downhole conditions;
- Imitates the conductivity and permeability of fresh water, and therefore maintains the same level of fracturing performance that operators achieve using 100% fresh water.
The WaterSure Fluid Treatment Process
1.Filter Suspended Solids
We understand that you may not have the necessary equipment to filter produced water at your job site, so we’ve teamed up with Omni Water Solutions. With minimal to no chemical treatment, the onsite Omni system filters from produced water all suspended solids that can hinder fracturing performance, and the system clarifies water down to the 15-micron to submicron level. Because interfering ions, salinity, boron, calcium, and chlorides have no effect on WaterSure fluid performance, their removal is unnecessary, which reduces your treatment costs. The filtered waste can be disposed of in an environmentally safe manner.
2.Oxidization
Without any harm to the environment, the addition of chloride dioxide (ClO2) to filtered water kills bacteria that can sour your well while helping to decrease reservoir pressure and improve the permeability, wetness, and porosity of the formation, which can increase production rates. ClO2 won’t affect the pH balance in your well or react with most organics and ammonia. We choose ClO2 as a biocide because the U.S. Environmental Protection Agency (EPA) recognizes it as a powerful yet safe water disinfectant per the Safe Water Drinking Act (SWDA) of 1974.
3.Ready for Stimulation
We combine filtered water with an environmentally friendly gelling agent and crosslinker to create fluids with excellent proppant transport and conductivity. WaterSure fluids handle salt concentration in excess of 300,000 parts per million (ppm), between 5,000 to 30,000 ppm of divalent ions, and greater than 400 ppm of boron and 185,000 ppm of chlorides. Additionally, the fluids perform well within temperatures from 100°F to 300°F (38°C to 149°C). With the addition of our specialized crosslinkers, WaterSure fluids maintain high, closely controlled viscosity levels that are sufficient to carry proppant during long periods of exposure to high temperatures and bottomhole pressures.
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